Nippon Oil Company

Nippon Paint Compnay, Ltd.

Akio Oshima

Shozo Tsuchiya

Hideo Hayashi

Yutaka Otsuki

Yoshihiko Araki

Yasuyuki Tsuchiya

Hiroyoshi Omika

Makoto Sasaki

Hisatake Sato

Hideo Hayshi

A cathode-depositing electrodeposition coating composition having excellent low-temperature curability comprising as essential ingredients (A) 100 parts by weight of a reaction product of (1) a high molecular compound having a molecular weight of 500 to 5,000 and containing carbon-carbon double bonds with an iodine number of 50 to 500 and 3 to 12% by weight of oxirane oxygen, and (2) 30 to 300 millimoles, per 100 g of the high molecular compound (1), of a specified amine compound, (B) 10 to 200 parts by weight of a reaction product of a specified diglycidyl compound with 1.9 to 2.1 moles, per molecule of the diglycidyl compound, of an alpha, beta-unsaturated carboxylic acid or an unsaturated fatty acid having a molecular weight of 100 to 350 and containing at least 10% by weight of a carbon-carbon double bond, or a mixture of both, (C) 0.5 to 10 parts by weight of a reaction product of a high molecular compound having a molecular weight of 500 to 5,000 and containing a carbon-carbon double bond with an iodine number of 50 to 500 and 40 to 400 millimoles, per 100 g of the high molecular compound, of a specified alpha, beta-unsaturated dicarboxylic acid and (D) 0.005 to 1.0 part by weight, as metal, of a water-soluble salt of an organic acid with a metal selected from manganese, cobalt, and copper.

Cathode-depositing electrodeposition coating composition

A cathode-depositing electrodeposition coating composition comprising an aqueous solution or dispersion containing

The present invention is directed to a printing ink composition containing the reaction product of 5 to 100 parts by weight of a phenolic resin and about 100 parts by weight of a resin modified with an acid. The phenolic resin is prepared by condensing an appropriate 4-9 carbon alkylphenol with formalin. The modified resin is prepared by reacting 1 to 15 parts by weight of an appropriate unsaturated carboxylic acid and/or anhydride with about 100 parts by weight of the reaction product of 5 to 100 parts by weight straight-chain .alpha.-olefin with about 100 parts by weight of an appropriate pentacyclic compound, such as cyclopentadiene and/or dicyclopentadiene.

Offset printing ink composition

A cathode-precipitating electrodeposition coating having excellent low-temperature curability, said composition consisting essentially of

According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below: ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers not less than 1 and are in the relation of m+n=6; and/or a Diels-Alder addition product thereof (A) with a co-dimer (component B) of said five-member cyclic compound and 1,3-butadiene by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 200.degree. C. to 350.degree. C. Also disclosed are a process for hydrogenating said novel resin to produce a novel hydrogenated resin and resin compositions containing said hydrogenated resin.

Process for producing novel hydrogenated resin from five-member cyclic

According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below:

Novel hydrogenated resin produced from five-member cyclic compounds

A hot melt adhesive composition comprising (I) a hydrogenated resin having a softening point of 60.degree.-130.degree. C. obtained by the hydrogenation of a copolymer resin prepared by reacting (A) at least one five-membered cyclic compound such as cyclopentadiene with (B) at least one dimer or trimer of the five-membered cyclic compound, isoprene and piperylene in specified ratios by weight, and (II) an ethylene type copolymer and/or wax.

Hot melt adhesive compositions comprising hydrogenated resin and

According to the invention there is provided a hot melt composition comprising (A) a hydrogenated resin having a softening point ranging from 60.degree. C. to 130.degree. C., said hydrogenated resin (A) being prepared by hydrogenating a resin at a hydrogenation percentage of aromatic rings of from 10 to 90%, said resin being prepared by copolymerizing at least two components comprising (a) 100 parts by weight of cyclopentadiene or its derivative selected from the group consisting of cyclopentadiene and dicyclopentadiene and an alkyl substituent thereof and (b) 5 to 50 parts by weight of indene or its derivative selected from the group consisting of indene and an alkyl substituent thereof and (B) one or more compound selected from the group consisting of ethylene-unsaturated ester copolymers, polyester resins and waxes.

Hot melt composition

A resin for printing inks, prepared by the reaction of (A) a conjugated double bond-containing five-membered cyclic compound such as dicyclopentadiene, (B) a phenolic compound such as phenol, (C) an unsaturated carboxylic acid such as maleic anhydride and (D) a resol-type phenol resin obtained from phenol or an alkyl-substituted phenol and formaldehyde. In one embodiment, this invention relates to a process for the preparation of said resin for printing inks.

Resins for printing inks

Printing ink composition characterized by containing as a vehicle a resin having a softening point of 100.degree. C. or more and acid value of 5 to 50, said resin being obtained by reacting the following three components A, B and C, i.e., cyclopentadiene, dicyclopentadiene or their alkyl substituted derivatives as the A component an .alpha.,.beta.-unsaturated monocarboxylic acid as the B component and alkyl esters of said monocarboxylic acid as the C component, in proportions of such amounts as to satisfy the following formulae, ##EQU1## at a temperature in the range of 150.degree. - 350.degree. C. in the absence of a catalyst.

Printing ink composition

Resins for printing ink and particularly offset ink, are produced by reacting a resin obtained by heat polymerizing at least one of cyclopentadiene, dicyclopentadiene or their alkyl substituted derivatives with 1-3 carbons and an unsaturated alcohol or unsaturated alcohol ester of an organic acid at a temperature of 150-350.degree. C. in the presence or in the absence of an inert hydrocarbon solvent with a higher monohydric saturated fatty acid or higher monohydric unsaturated fatty acid or their mixtures to produce a resin having a softening point of 100.degree. C or more.

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Yokohama, Japan

Akio Oshima