The Furukawa Electric Co., Ltd.

Furukawa Metals Co., Ltd.

Akio Nojiri

Toshio Koreeda

Takashi Sawasaki

Naonori Shiina

Masao Horiguch

Hirokazu Komatsu

Isamu Noguchi

Masao Horiguchi

Isamu Namiki

Hideyo Ueno

Hidehito Shishikura

Junnosuke Sasazima

Shinji Onobori

Kenji Mogi

Hiroshi Nagai

Hlroyuki Nakae

Junnosuke Sasajima

According to a method of manufacturing a foamed polypropylene resin sheet of this invention, a composition comprising as a resin component a mixture of 80 to 20 wt % of a crystalline propylene-ethylene block copolymer containing 20 wt % or less of ethylene and having a melt index (MI) of 2 or less and 20 to 80 wt % of a crystalline propylene-ethylene block or random copolymer containing 5 wt % or less of ethylene and having an MI of 6 to 20 or a polypropylene homopolymer having an MI of 6 to 20 is used. A pair of molding roll dies is horizontally arranged at a point separated from the center of an apex of an extrusion foaming die when a foamed sheet is to be extrusion-molded. A distance between the center of the roll and the apex of a base lip is set to fall within a range of (R.sup.2 +25).sup.1/2 to (R.sup.2 +144).sup.1/2 where R is a radius of the molding roll die. The composition is extrusion-molded into a foamed sheet without collapsing while a fluid is supplied to the interiors of the rolls so that a surface temperature of the foamed sheet passing between the molding rolls is set at 105.degree. C. or less. The extrusion-molded foamed sheet is cooled thereafter.

Method of manufacturing foamed polypropylene resin sheet

A heat insulating pipe has a foamed heat insulating layer on its outer circumferential face in which the heat insulating layer has an expansion ratio of at least 4 and is of a three-layered structure consisting of a middle foamed layer and lower and upper foamed layers formed at both sides of the middle foamed layer. The cells of the middle foamed layer are relatively large. The cells of the upper foamed layer and the lower foamed layer are relatively small. The shapes of the cells of the middle foamed layer are such that, for the average cell diameter (.mu..sub.1) measured in the radial direction of the pipe and the average cell diameter (.mu..sub.2) measured in the axial direction of the pipe, the relation of .mu..sub.1 /.mu..sub.2 =0.3-0.9 holds.

Heat insulating pipe

Cross-linked polyvinyl chloride resin foam and method of manufacturing

In producing a crosslinked polypropylene foam, 0.5 to 4 parts by weight of a compound selected from triacrylate and trimethacrylate of aliphatic polyhydric alcohol and a blowing agent are mixed with 100 parts by weight of propylene homopolymer or copolymer. Then, the mixture is shaped under heat, followed by irradiation with an ionizing radiation such that the dose of the radiation absorbed by the shaped mass ranges between 0.1 and 10 Mrad. Finally, the irradiated mass is heated for foaming.

Crosslinkable polypropylene composition

A composition for a crosslinked polyolefin foam is prepared from 20 to 75% by weight of a crystalline propylene copolymer containing 1 to 15% by weight of ethylene and having a crystallinity higher than 50% and 80 to 25% by weight of polyethylene.

Composition for a crosslinked polyolefin foam

A method for manufacturing a heat insulating pipe having a foamed insulating layer around the outer surface of said pipe. The foamed insulating layer has an expansion ratio of at least 4. It has three integral sub-layers, said sub-layers including a cellular middle foamed sub-layer which is integral with a cellular inner foamed sub-layer and a cellular outer foamed sub-layer, said inner and outer sub-layer being on opposite sides of said middle sub-layer, said cellular inner foamed sub-layer being the innermost sub-layer with respect to said pipe and surrounding the outer surface of said pipe. The cells of said inner and outer sub-layers are smaller than the cells of said middle cellular sub-layer, the ratio .mu..sub.1 /.mu..sub.2 of the cell dimensions of said cellular middle sub-layer are between 0.3 and 0.9, wherein .mu..sub.1 is the average cell dimension measured in the radial direction of said pipe and .mu..sub.2 is the average cell dimension measured in the axial direction of said pipe. The method for producing said 3 sub-layered foamed insulating layer comprises passing a pipe heated to a temperature of between 60.degree. C. and 120.degree. C. through the nipple of a cross-head die and simultaneously extruding a mixture of a propylene-ethylene block polymer having an ethylene content of between 1 and 20% by weight and a Melt Index of between 0.1 and 4 together with a foaming agent over the outer surface of said pipe to cause said mixture to expand and form said 3 sub-layered foamed insulating layer on said pipe, the relationship between the overall thickness t of the 3 sub-layered foamed insulating layer, the expansion ratio M of the 3 sub-layered foamed insulating layer, and the die-nipple distance d of a cross-head die being ##EQU1## wherein K=0.75 to 0.20.

Method for extrusion coating of a pipe with a foamed cover layer having

Method of producing crosslinked polypropylene foam

A method of crosslinking poly-.alpha.-olefin series resins, comprising the steps of subjecting a resin composition to graft reaction under a volume ratio of oxygen to the resin composition set at less than 0.1 and at temperatures ranging between the thermal decomposition temperature of the radical generating agent and 230.degree. C., said composition comprising at least one kind of poly-.alpha.-olefin series resin of polypropylene series resin, poly(butene-1) series resin or poly(4-methyl pentene-1) series resin; a radical generating agent of dibenzoyl peroxide or t-butyl perbenzoate; and a silane compound having the general formula of RR'SiY.sub.2, where 'R' is a monovalent olefinically unsaturated hydrocarbon group or hydrocarbonoxy group, 'Y' is an organic group capable of hydrolysis, and 'R'' is a monovalent hydrocarbon group except aliphatic unsaturated hydrocarbon groups, or the group 'Y' or 'R' defined above, and bringing the resultant graft polymer into contact with water so as to cause crosslinking reaction under the action of a silanol condensation catalyst added to the reaction system before or after the graft reaction step.

Method of crosslinking poly-.alpha.-olefin series resins

The present invention provides a foamable polyolefin composition comprising a polyolefin, a crosslinking agent, a blowing agent decomposable at temperatures higher than the decomposition temperature of said crosslinking agent and a gas trapping agent as well as a method for manufacturing foamed polyolefin from said foamable polyolefin composition.

Foamable polyolefin composition and method for manufacturing foamed

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Yokohama, Japan

Akio Nojiri