Mitsubishi Gas Chemical Company, Inc.

Akinori Tanaka

Mitsunori Oda

Shigeo Yoshinaka

Masakazu Furushima

Takashi Suzuki

Akinori Suzuki

Kazutoshi Kikkawa

Satoko Imaruoka

Toshio Kajita

Taketo Maruyama

Ryuji Hasemi

Yasushi Higuchi

Masaki Sugita

Satoshi Nanba

Takashi Oritani

Atsushi Inoue

Takako Uchiyama

Masaharu Doya

Suong B Hyeon

Torakazu Tahara

Be H Suong

Kazuko Tamano

Yuko Ebe

Noriko Tamano

Akiko Tamano

Yoshinori Sasaki

Yoshiaki Suzuki

Suong Be Hyeon

A method for efficiently separating and collecting an optically active amino acid amide and an optically active amino acid from an aqueous solution containing the optically active amino acid amide and the optically active amino acid includes separating and collecting an optically active amino acid amide from an aqueous solution containing the optically active amino acid amide and an optically active amino acid, utilizing a difference in solubility in an organic solvent between the optically active amino acid amide and the optically active amino acid, without desalting the aqueous solution or after desalting the same, under such a condition that a ratio (C/A) of the total equivalent (C) of cations to the total equivalent (A) of anions contained in the aqueous solution falls within the range from 0.95 to 1.05 when the aqueous solution is not desalted, and the range from 0.5 to 1.5 when the aqueous solution is desalted.

Method of separating and collecting optically active amino acid amide

There is provided a process for producing an optically active 2-alkylcysteine or a salt thereof, characterized by allowing cells of microorganism or treated products thereof having an activity of stereoselective hydrolysis of the amide bond of a 2-alkyl-L-cysteinamide or a salt thereof to act on a 2-alkylcysteinamide consisting of a mixture of D- and L-isomers or a salt thereof; and allowing the obtained 2-alkyl-L-cysteine and 2-alkyl-D-cysteinamide to react with an aldehyde or a ketone, or an acetal or ketal thereof, so as to derive therefrom a 4-alkylthiazolidine-4-carboxylic acid or a salt thereof and a 4-alkylthiazolidine-4-carboxamide or a salt thereof, thereby efficiently separating and obtaining a 2-alkyl-L-cysteine or a salt thereof, or a 2-alkyl-D-cysteine or a salt thereof. There is also provided a process for producing a 4-alkylthiazolidine-4-carboxylic acid or a salt thereof from the 2-alkylcysteine or a salt thereof.

Process for producing optically active 2-alkycysteine, derivative thereof, and processes for production

A method for separately collecting an optically active amino acid amide and an optically active amino acid from an aqueous solution containing same, together with at least one member selected from the group consisting of an acid, a base, and a salt, includes a step of neutralizing an acid or base in the aqueous solution, a desalting step of removing a salt contained in the aqueous solution and/or formed in the neutralization step, and a step of separately collecting the optically active amino acid amide/amino acid separately from the desalted aqueous solution by a process which takes advantage of a difference in solubility between the two components in an organic solvent. The desalting step is preferably performed by electrodialysis, optionally with ammonia added to the aqueous solution. The optically active amino acid amide/amino acid can be separately collected with high efficiency using an organic solvent.

Method of separately collecting optically active amino acid amide and optically active amino acid

A process for producing a 2-alkylcysteinamide, which comprises hydrolysis of a 4-alkylthiazolidine-4-carboxamide represented by the general formula (2) or a salt thereof: wherein R represents a lower alkyl group having 1&#x2013;4 carbon atoms; and each of Rand Rindependently represents hydrogen or a lower alkyl group having 1&#x2013;4 carbon atoms, or Rand Rare linked together to form an alicyclic, structure having 4&#x2013;7 carbon atoms, excluding the case where both Rand Rare hydrogen, to give a 2-alkylcysteinamide represented by the general formula (1) or a salt thereof wherein R represents a lower alkyl group having 1&#x2013;4 carbon atoms. Cells of a microorganism or treated products thereof having activity of stereoselective hydrolysis of a 2-alkyl-L-cysteinamide are allowed to act on the compound represented by the general formula (1) to yield a 2-alkyl-L-cysteine.

2-alkylcysteinamide or salt thereof, process for producing these, and use of these

A method for producing L-allysine acetal represented by general formula (II), comprising reacting D,L-allysinamide acetal represented by general formula (I) with cells of microorganism or treated cell product having an activity of stereoselectively hydrolyzing L-allysinamide acetal,

Method for producing L-allysine acetal

Disclosed are a phenoxyalkylamine represented by the following general formula I and a salt of said phenoxyalkylamine represented by the following general formula II: ##STR1## wherein R represents a linear saturated hydrocarbon having 7 to 12 carbon atoms, n is an integer of from 1 to 5, m is an integer of from 2 to 4, and HX represents a mineral acid. These compounds have strong bacteriostatic and bactericidal actions for plants with no phytotoxicity. Therefore, these compounds are effectively used as the active ingredient of an agricultural and horticultural bactericide.

Phenoxyalkylamine and agricultural and horticultural bactericide

Disclosed is an N-benzyl-N-phenoxyethylamine selected from the group consisting of the N-benzyl-N-phenoxyethylamine represented by the following formula (I): ##STR1## and an agriculturally acceptable acid addition salt represented by the following formula (II): ##STR2## wherein m represents a number of 1 or 2 with a proviso that when m is 1 and a chlorine atom in the ring A is present at para(4)-position of the ring A, two chlorine atoms in the ring B are present at 2,3-, 2,5-, 2,6-, 3,4- or 3,5-positions of the ring B, and HX represents an acid.

N-benzyl-n-phenoxyethylamines and agricultural and horticultural

Disclosed are novel adenine derivatives represented by the formula I and agriculturally acceptable acid addition salts thereof represented by the formula: ##STR1## wherein n is an integer of 2-4. Compositions for increasing yield of crops such as leguminous crops and gramineous crops which contain the above adenine derivatives or salts thereof as an active ingredient and methods for increasing yield of crops using these compositions are also disclosed.

Adenine derivatives and their use as agents for increasing yield of crops

Disclosed is an N-benzyl-N-phenoxyethylamine selected from the group consisting of the N-benzyl-N-phenoxyethylamine represented by the following formula (I): ##STR1## and an agriculturally acceptable acid addition salt represented by the following formula (II): ##STR2## wherein m represents a number of 1 or 2 with a proviso that when m is 1 and a chlorine atom in the ring A is present at para(4)-position of the ring A, two chlorine atoms in the ring B are present at 2,3-, 2,5-, 2,6-, 3,4- or 3,5-positions of the ring B and HX represents an acid.

N-benzyl-N-phenoxyethylamines and agricultural and horticultural

A denine derivatives represented by the following formula: ##STR1## (wherein n is 1 or 2 and R and R' represent hydrogen or a methyl, ethyl, allyl, or propargyl group) and agriculturally acceptable acid addition salts thereof, which have cytokinin activity and besides, excellent rooting action, is applied to as plant growth regulators.

Adenine derivatives and their use as a plant growth regulator

This invention relates to use of compounds of the formula ##STR1## wherein R represents a C.sub.2-5 alkyl, C.sub.2-5 alkenyl or C.sub.2-5 alkynyl group, and X represents a hydrogen atom, a C.sub.2-8 alkylcarbonyl, carbamoyl, benzoyl, chloromethylcarbonyl or methoxycarbonyl group, or --PO.sub.3 H.sub.2, and Y represents a chlorine or bromine atom in promoting the growth of plants.

Plant growth promotion

Use of agriculturally acceptable salts of compounds of the following formula for promoting the growth of plants. ##STR1## wherein Hal represents a chlorine, bromine or iodine atom, X.sub.1 represents a hydrogen or chlorine atom, or a methyl, trifluoromethyl, nitro, methoxy or t-butyl group, and X.sub.2 represents a hydrogen atom, or both X.sub.1 and X.sub.2 represent a chlorine atom or a methyl group; and Y represents a hydrogen atom, or a C.sub.2-6 alkylcarbonyl, benzoyl, N-phenylcarbamoyl, N-3,4-dichlorophenylcarbamoyl, chloropropylcarbonyl, methoxycarbonyl, carbamoyl or methacryloyl group.

A plant growth regulating composition comprising as an active ingredient a combination of

Growing community of inventors

Niigata, Japan

Akinori Tanaka