Sharp Laboratories of America, Inc

Akinori Hashimura

Apostolos T Voutsas

Liang Tang

Douglas James Tweet

Gary Hinch

David R Evans

Paul John Schuele

Jiandong Huang

Alexey Y Koposov

Byron Cocilovo

An energy-generating transparent (EGT) structure is provided, in addition to a method for generating energy from light incident to an EGT structure. The EGT structure is made up of a window pane with an interior surface adjacent a reflective structure. The method accepts light incident to an exterior surface of the window pane, and transmits light in the visible spectrum through the window pane and reflective structure. However, light in the near-infrared (NIR) spectrum is reflected back from the reflective structure into the window pane, so that reflected NIR, spectrum light is supplied to an edge of the window pane. For example, reflected NIR spectrum light is supplied to the window pane edge if the light has an angle greater than or equal to an angle TIR occurring between the window pane exterior surface and air. This reflected NIR spectrum light can be converted to electrical or thermal energy.

Energy generating transparent film

An energy-efficient transparent solar film is presented. The solar film has a first film layer with metal nanostructures. The metal nanostructures have plasmon resonances in wavelength bands greater than, or both less than and greater than visible wavelengths, depending on size and shape. The metal nanostructures have no plasmon resonance at visible wavelengths. In another aspect, metal oxide nanocrystals are formed with the first film layer. The metal oxide nanocrystals have absorption in a band of wavelengths less than visible wavelengths, and absorption in a band of wavelengths greater than visible wavelengths. Also provided is a solar film window and fabricating method.

Energy-efficient transparent solar film

A plasmonic optical device is provided operating in near ultra violet (UV) and visible wavelengths of light. The optical device is made from a substrate and nanoparticles. The nanoparticles have a core with a negative real value relative permittivity of absolute value greater than 10 in a first range of wavelengths including near UV and visible wavelengths of light, and a shell with an imaginary relative permittivity of less than 5 in the first range of wavelengths. A dielectric overlies the substrate, and is embedded with the nanoparticles. If the substrate is reflective, a reflective optical filter is formed. If the substrate is transparent, the filter is transmissive. In one aspect, the dielectric is a tunable medium (e.g., liquid crystal) having an index of refraction responsive to an electric field. The tunable medium is interposed between a first electrode and a second electrode.

Air stable, color tunable plasmonic structures for ultraviolet (UV) and visible wavelength applications

A method is provided for forming a reflective plasmonic display. The method provides a substrate and deposits a bottom dielectric layer. A conductive film is deposited overlying the bottom dielectric layer. A hard mask is formed with nano-size openings overlying the conductive film. The conductive film is plasma etched via nano-size openings in the hard mask, stopping at the dielectric layer. After removing the hard mask, a conductive film is left with nano-size openings to the dielectric layer. Metal is deposited in the nano-size openings, creating a pattern of metallic nanoparticles overlying the dielectric layer. Then, the conductive film is removed. The hard mask may be formed by conformally depositing an Al film overlying the conductive film and anodizing the Al film, creating a hard mask of porous anodized Al oxide (AAO) film. The porous AAO film may form a short-range hexagonal, and long-range random order hole patterns.

Plasmonic reflective display fabricated using anodized aluminum oxide

A method is provided for improving metallic nanostructure stability. The method provides a substrate, and using a physical vapor deposition (PVD) process for example, deposits metallic nanostructures having a first diameter overlying the substrate. Some examples of metallic nanostructures include Ag, Au, and Al. The metallic nanostructures are annealed in an atmosphere including an inert gas and H. The annealing temperature is less than the melting temperature the metal material in bulk form. In response to the annealing, stabilized metallic nanostructures are formed. If the stabilized metallic nanostructures are exposed to an ambient air environment the stabilized metallic nanostructure maintain the first diameter. Typically, the metallic nanostructures are initially formed having a rectangular shape with corners. After annealing, the stabilized metallic nanostructures have a dome shape.

Method for improving metallic nanostructure stability

A plasmonic polarizer and a method for fabricating the plasmonic polarizer are provided. The method deposits alternating layers of non-metallic film and metal, forming a stack. A hard mask is formed overlying the stack. The hard mask comprises structures having dimensions and periods between adjacent structures less than a first length, where the first length is equal to (a first wavelength of light/2). The stack is etched through openings in the hard mask to form pillar stacks of alternating non-metallic and metal layers having the dimensions of the hard mask structures. Then, the hard mask structures are removed. In one aspect, subsequent to removing the hard mask structures, the spaces between the pillar stacks are filled with a dielectric material.

Plasmonic in-cell polarizer

An electrical pressure sensor is provided with a method for measuring pressure applied to a sensor surface. The method provides an electrical pressure sensor including a sealed chamber with a top surface, first electrode, second electrode, an elastic polymer medium, and metallic nanoparticles distributed in the elastic polymer medium. When the top surface of the sensor is deformed in response to an applied pressure, the elastic polymer medium is compressed. In response to decreasing the metallic nanoparticle-to-metallic nanoparticle mean distance between metallic nanoparticles, the electrical resistance is decreased between the first and second electrodes through the elastic polymer medium.

Metallic nanoparticle pressure sensor

An electrical pressure-sensitive reflective display includes an array of display pixels, each with a transparent top surface, first electrode, second electrode, an elastic polymer medium, and metallic nanoparticles distributed in the elastic polymer medium. When a first voltage potential is applied between the first and second electrodes of each display pixel, a first color is reflected from the incident spectrum of light, assuming no pressure is applied on the top surface of each display pixel. When the top surface of a first display pixel is deformed in response to an applied pressure, the elastic polymer medium in the first display pixel is compressed, decreasing the metallic nanoparticle-to-metallic nanoparticle mean distance in the first display pixel. In response to decreasing the metallic nanoparticle-to-metallic nanoparticle mean distance, the color reflected from the incident spectrum of light by the second display pixel is changed from the first color to second color.

Touch-enabled plasmonic reflective display

A plasmonic display device is provided that uses physical modulation mechanisms. The device is made from an electrically conductive bottom electrode and a first dielectric layer overlying the bottom electrode. The first dielectric layer is a piezoelectric material having an index of expansion responsive to an electric field. An electrically conductive top electrode overlies the first dielectric layer. A first plasmonic layer, including a plurality of discrete plasmonic particles, is interposed between the top and bottom electrodes and in contact with the first dielectric layer. In one aspect, the plasmonic particles are an expandable polymer material covered with a metal coating having a size responsive to an electric field.

Physical modulation tuned plasmonic device

A method is provided for color tuning a plasmonic device with a color tunable electronic skin. A plasmonic electronic skin is used, including a first substrate, a plasmonic structure, an electrically conductive transparent first electrode layer, an electrically conductive transparent second electrode layer, and a polymer-networked liquid crystal (PNLC) layer interposed between the first and second transparent electrode layers. In response to receiving a color tuning voltage, a full visible spectrum incident light, and a PNLC switch voltage, the plasmonic structure generates a first primary color. A primary color exhibits a single wavelength peak with a spectral full width at half magnitudes (FWHMs) in the visible spectrum of light. In response to receiving the PNLC switch voltage between the first and second electrode layers, the PNLC layer passes incident light.

Plasmonic electronic skin

A plasmonic display device is provided with liquid crystal dipole molecule control. The device is made from a first set of electrodes including at least one electrically conductive top electrode and at least one electrically conductive bottom electrode capable of generating a first electric field in a first direction. A second set of electrodes, including an electrically conductive right electrode and an electrically conductive left electrode, is capable of generating a second electric field in a second first direction. A dielectric layer overlies the bottom electrode, made from a liquid crystal material with molecules having dipoles responsive to an electric field. A plasmonic layer, including a plurality of discrete plasmonic particles, is interposed between the first and second set of electrodes and in contact with the dielectric layer. In one aspect, the plasmonic layer is embedded in the dielectric layer.

Plasmonic device tuned using liquid crystal molecule dipole control

A plasmonic display device is provided having dual modulation mechanisms. The device has an electrically conductive bottom electrode that may be either transparent or reflective. A dielectric layer overlies the bottom electrode, made from an elastic polymer material having a refractive index responsive to an electric field. An electrically conductive top electrode, either transparent or reflective, overlies the dielectric layer. A plasmonic layer, including a plurality of discrete plasmonic particles, is interposed between the top and bottom electrodes and in contact with the dielectric layer. In one aspect, the plasmonic layer is embedded in the dielectric layer. Alternately, the plasmonic layer overlies the bottom (or top) electrode. Then, the dielectric layer overlies the plasmonic layer particles and exposed regions of the bottom electrode between the first plasmonic layer particles.

Plasmonic device tuned using elastic and refractive modulation mechanisms

A display device is provided for reflecting a black color, as enabled by an optical splitting photonic liquid crystal waveguide. Sets of top and bottom electrodes are formed in a periodic pattern. A first dielectric layer overlies the set of bottom electrodes, made from a liquid crystal (LC) material with molecules having dipoles responsive to an electric field. A plasmonic layer, including a plurality of discrete plasmonic particles, is interposed between the sets of top and bottom electrodes, and is in contact with the first dielectric layer. A voltage potential is applied between the top and bottom electrodes, generating an electric field. Dipole local orientation and non-orientation regions are created in the liquid crystal molecules in response to the electric field, and a wavelength of light outside the visible spectrum is reflected in response to optical spectrum splitting of the incident light.

Optical spectrum splitting for black color display

Plasmonic device tuned using physical modulation

A color-tunable plasmonic device is provided with a partially modulated refractive index. A first dielectric layer overlies a bottom electrode, and has a refractive index non-responsive to an electric field. A second dielectric layer overlies the first dielectric layer, having a refractive index responsive to an electric field. An electrically conductive top electrode overlies the second dielectric layer. A plasmonic layer including a plurality of discrete plasmonic particles is interposed between the top and bottom electrodes. In one aspect, the plasmonic layer is interposed between the first and second dielectric layers. In a second aspect, the plasmonic layer is interposed between the first dielectric layer and the bottom electrode. In a third aspect, a first plasmonic layer is interposed between the first dielectric layer and the bottom electrode, and a second plasmonic layer of discrete plasmonic particles is interposed between the first dielectric layer and the second dielectric layer.

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Vancouver, WA, United States of America

Akinori Hashimura