Matsushita Electric Industrial Co., Ltd.

Akiko Miyahara

Kohji Yuasa

Susumu Kikuyama

Takashi Ebihara

Xianglong Wang

Kazutaka Ikeda

The hydrogen storage alloy electrode comprises: a conductive core material; and an active material layer which contains a hydrogen storage alloy powder and is carried on said core material, and the alloy powder has any shape selected from the group consisting of spherical shapes, substantially spherical shapes and oval shapes. The core material comprises: a conductive sheet; and fibrous or columnar sintered nickel pieces bonded to the surface of the conductive sheet. Alternatively, the active material layer comprises: an active material layer A which contains a hydrogen storage alloy powder A with a mean particle size 'a' and is carried on said core material; and an active material layer B which contains a hydrogen storage alloy powder B with a mean particle size 'b' and is carried on said active material layer A (wherein a&#x3c;b). Alternatively, the active material layer further contains a crushed alloy powder having on the surface thereof at least one selected from the group consisting of nickel and cobalt. The use of such electrode provides an alkaline storage battery excellent in both discharge characteristics and cycle life.

Alkaline storage battery and hydrogen storage alloy electrode used therefor

An alkaline storage battery which is excellent in charge and discharge cycle life characteristics and high-rate discharge characteristics is provided by constructing it using an electrode made of an MmNi type hydrogen-absorbing alloy powders having modified surface. The alkaline storage battery comprises a negative electrode made using a hydrogen-absorbing alloy in the form of powders comprising at least one rare earth element, nickel and at least one transition metal in which the surface portion of the alloy has nickel in metallic state exposed at the surface, pores positioned between the nickel and the nickel, and a nickel-rich layer present on the alloy surface contacting with the pores, a positive electrode made using a metal oxide, a separator, and an alkaline electrolyte.

Hydrogen-absorbing alloy for battery, method for producing the same, and alkaline storage battery using the same

The present invention provides an alkaline storage battery excellent in high-rate charge and discharge characteristics, and a hydrogen-absorbing alloy electrode suitable for the battery and a method for producing the same. The hydrogen-absorbing alloy is preferably produced by wet grinding in water a hydrogen-absorbing alloy having at least one rare earth element, nickel and at least one transition metal element, treating the resulting alloy powders in an aqueous alkali solution, and then consecutively treating the powders in an acidic aqueous solution. The hydrogen-absorbing alloy powders have a structure of a nickel-condensed layer being exposed and have many pores.

Alkaline storage battery, hydrogen-absorbing alloy electrode and method for producing the same

The present invention provides an alkaline storage battery excellent in high-rate charge and discharge characteristics, and a hydrogen-absorbing alloy electrode suitable for the battery and a method for producing the same. The hydrogen-absorbing alloy is preferably produced by wet grinding in water a hydrogen-absorbing alloy comprising at least one rare earth element, nickel and at least one transition metal element, treating the resulting alloy powders in an aqueous alkali solution, and then consecutively treating the powders in an acidic aqueous solution. The hydrogen-absorbing alloy powders have a structure of a nickel-condensed layer being exposed and have many pores.

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Chigasaki, Japan

Akiko Miyahara