Other

Mitsui Chemicals, Inc.

Kaneka Corporation

Toagosei Company, Ltd.

Akihiro Sakata

Koji Saiki

Shinji Katayama

Kenzo Yamaguchi

Hiroaki Aikawa

Takeshi Watanabe

Nagakazu Furuya

Provided is a process which permits, upon preparation of chlorine and a caustic alkali by electrolyzing an aqueous alkali chloride solution in an ion-exchange-membrane-method alkali chloride electrolytic cell equipped with a gas diffusion cathode, decrease of an excess ratio of an oxygen containing gas to be fed newly to the gas diffusion cathode and facilitates temperature control of the electrolytic cell. A process for electrolyzing an alkali chloride comprising: introducing saline water into an anode chamber of an ion-exchange-membrane-method alkali chloride electrolytic cell equipped with a gas diffusion cathode; and introducing an oxygen-containing gas into a gas chamber of a gas diffusion cathode, to thereby obtain chlorine in the anode chamber and an aqueous caustic alkali solution in the cathode chamber.

Method for electrolysis of alkali chloride

A method of operating an alkali chloride electrolytic cell, comprising: providing an alkali chloride electrolytic cell comprising a gas diffusion cathode and a cation-exchange membrane, the gas diffusion cathode and cation-exchange membrane defining a caustic chamber; allowing a caustic alkali aqueous solution to flow in the caustic chamber at a linear velocity of at least 1 cm/sec.

Method of operating alkali chloride electrolytic cell

An electrolytic cell using an oxygen cathode, for use in an ion-exchange membrane electrolytic soda process or the like, the electrolytic cell having; a structure, wherein, for effective supply and discharge of a caustic liquid and for an effective handling of a caustic liquid leakage, provided on an outer-side edge of the electrolytic cell are an upper chamber as a caustic liquid discharge outlet, a lower chamber as a caustic liquid introduction inlet, and a caustic-liquid room frame connected via a caustic liquid passage to thereby reduce a caustic liquid leakage; a structure, wherein a lower gas chamber is provided at the lower outer end of a cathode element to thereby handle a caustic liquid leakage from a gas diffusion electrode to a gas room; or a structure which uses a gas-liquid permeating gas diffusion electrode to supply an oxygen gas from an upper chamber communicating with a gas room and discharge a gas and a caustic liquid into a lower chamber.

Electrolytic cell using gas diffusion electrode and power distribution method for the electrolytic cell

An electricity leading method for a gas diffusion electrode is provided, by which a gas diffusion electrode is easily fixed to a cathode current collecting frame, the contact part has reduced electrical resistance, even an electrically insulating mesh sheet can be utilized as a gas chamber, and only the gas diffusion electrode can be replaced in renewal of the electrode. The method includes preparing a gas diffusion electrode by sandwiching a conductor made of a highly conductive metallic mesh or spongy processed material in catalyst layers or attaching a catalyst layer onto the conductor while leaving the conductor exposed in the outer periphery of the electrode, and electrically connecting the exposed part of the conductor to a cathode chamber current collecting frame.

Method for reducing charge in gas diffusing electrode and its charge reducing structure

A sodium chloride electrolytic cell is provided, comprising a gas diffusion electrode that allows smooth supply and discharge of catholyte for electrolyzing sodium chloride and allows oxygen gas to come in good contact therewith. The sodium chloride electrolytic cell comprises an anode chamber having an anode into which an aqueous solution of sodium chloride and a cathode chamber having the foregoing gas diffusion electrode for producing an alkaline aqueous solution, the anode chamber and the cathode chamber being divided by an ion exchange membrane. The sodium chloride electrolytic cell is arranged to effect electrolysis in such a manner that there occurs no pressure differential between the catholyte chamber and the gas chamber in the gas diffusion electrode. Further, a nickel mesh substance is fitted in a concave portion having the same size as that of the gas diffusion electrode formed in the central portion of a thin nickel plate.

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Tokyo, Japan

Akihiro Sakata