Honda Motor Co., Ltd.

Massachusetts Institute of Technology

University of Central Florida Research Foundation Inc

Akihiro Kushima

Ju Li

Yoshiya Fujiwara

Tetsuya Koido

Supriya Koul

Chao Wang

Yoshiyuki Morita

Hiroshi Ogasa

Yang Yang

Kun Liang

Fumika Fujisaki

Junjie Niu

A lithium (Li) secondary battery having a Li buffer layer compressed between a Li metal anode and an electrolyte of the battery cell and a porous structure positioned between the Li metal anode and a current collector of the battery cell. The Li buffer layer is effective in preventing uncontrollable dendrite growth. The porous structure layer is effective in guiding the location of the Li deposition, thereby reducing the volume changes of the Li anode during the charge and discharge cycles of the lithium secondary battery.

Lithium secondary battery and method of manufacture

Enabling the use of lithium metal as an anode electrode is a key for developing next generation energy storage device beyond current lithium ion battery technology. However, there are major obstacles that need to be overcome before it can be used in commercial applications; specifically, dendrite formation can short the cell, and electrolyte decomposition contributes to decreased battery lifetimes. Each obstacle can be overcome by coating a lithium metal anode with a liquid metal buffer that enables uniform deposition of lithium ions thereon, preventing dendritic growth and forming a stable solid electrolyte interface to separate the lithium metal anode from the electrolyte within a battery cell. The liquid metal buffer becomes a semi-liquid buffer when contributing to forming a solid electrolyte interface, and can regain its liquid state when the lithium ions flow to the cathode of the battery cell.

Liquid metal buffer layer for lithium batteries

The present invention is directed to lithium-sulfur batteries exhibiting a high capacity, high cycle life with low production cost and improved safety.

Sulfur nanosponge cathode for lithium&#x2014;sulfur battery and methods of manufacture thereof

An air secondary battery has a positive electrode to which an oxygen-containing gas is supplied, a negative electrode containing a metal active material, and an electrolytic solution through which a metal ion generated from the metal active material is transported. The positive electrode contains a composite containing a matrix and a zeolite disposed in the matrix. The matrix is in the form of a porous body which the electrolytic solution permeates. In the matrix, the zeolite has an oxygen-containing gas passage through which only the oxygen-containing gas can flow.

Air secondary battery

An air secondary battery has a cathode to which an oxygen-containing gas is supplied, an anode containing an active metal material, and an electrolyte interposed between the cathode and the anode. In a discharge process, metal ions are generated from the active metal material, transferred through the electrolyte, and then reacted and bonded with oxygen molecules in the oxygen-containing gas on the cathode. Thus, the oxygen is reduced to generate a metal oxide. The cathode has a trap portion for confining the metal oxide. For example, the cathode has a first cathode layer and a second cathode layer having different average pore diameters. The first cathode layer located adjacent to the electrolyte and having a smaller average pore diameter acts as the trap portion.

Air secondary battery including cathode having trap portion

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Arlington, MA, United States of America

Akihiro Kushima