Dow Corning Corporation

Ajay K Dhaul

Roland L Halm

Richard G Johnson

Kirk M Chadwick

Robert D Steinmeyer

Timothy Rex Bunce

Ronald E Lund

The present invention is an improved process for preparing a portland cement composition where the process comprises heat calcining a mixture comprising a source of calcium and a source of silicon to form clinker. The improvement comprises providing to the process a silicon containing product resulting from the hydrolysis of chlorosilicon by-product as at least a portion of the source of silicon.

Hydrolyzed chlorosilicon by-product addition to cement

The present invention is a process for converting a high-boiling component resulting from the reaction of an organochloride with silicon into commercially more desirable monosilanes. The process comprises contacting the high-boiling component with hydrogen gas at a temperature within a range having a lower limit greater than 250.degree. C. and an upper limit of 1000.degree. C. Yield of the present process may be improved by use of a catalyst selected from a group consisting of activated carbon, platinum metal, platinum supported on alumina, palladium supported on carbon, SbCl.sub.5, H.sub.2 PtCl.sub.6, BCl.sub.3, AlCl.sub.3, and AlCl.sub.3 supported on a support material selected from a group consisting of carbon, alumina, and silica. In a preferred embodiment of the present process the process is run at a pressure within a range of about 250-1000 psig. The present process is preferential for the production of diorganodichlorosilane in relation to organotrichlorosilane in the monosilane product.

Conversion of direct process high-boiling component to silane monomers

The present invention is a process for converting a high-boiling component resulting from the reaction of an organochloride with silicon into commercially more desirable monosilanes. The process comprises contacting the high-boiling component with chlorine at a temperature within a range of about 250.degree. C. to 1000.degree. C. Improved yield of monosilanes can be obtained in the process by the use of a catalyst selected from a group consisting of alumina, silica. activated carbon, AlCl.sub.3, and AlCl.sub.3 supported on a support selected from a group consisting of alumina, silica, and carbon.

Conversion of direct process high-boiling component to chlorosilane

The present invention is a process for converting a high-boiling component resulting from the reaction of an organochloride with silicon into commercially more desirable monosilanes. The process comprises contacting the high-boiling component with hydrogen chloride and hydrogen gas at a temperature within a range of about 250.degree. C. to 1000.degree. C. in the presence of a catalyst selected from a group consisting of activated carbon, alumina, silica, zeolite, AlCl.sub.3, AlCl.sub.3 supported on a support selected from a group consisting of carbon, silica, and alumina; platinum supported on a support selected from a group consisting of carbon, silica, and alumina; and palladium supported on a support selected from a group consisting of carbon, silica, and alumina.

Catalytic conversion of direct process high-boiling component to

The present invention is a process for converting a high-boiling component resulting from the reaction of an organochloride with silicon into commercially more desirable monosilanes. The process comprises contacting the high-boiling component with hydrogen chloride at a temperature within a range of about 250.degree. C. to 1000.degree. C. in the presence of a catalyst selected from a group consisting of activated carbon, platinum supported on alumina, zeolite, AlCl.sub.3, and AlCl.sub.3 supported on a support selected from a group consisting of carbon, alumina, and silica.

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Carrollton, KY, United States of America

Ajay K Dhaul