Deutsche Texaco Aktiengesellschaft

Rwe-dea Aktiengesellschaft Fur Mineraloel Und Chemie

Adolf Buschfeld

Gerd Ripkens

Hans Schittek

Matthias Lattekamp

Dragomir Simic

Hans-Jurgen Krezmin

Manfred Gramse

Process for producing urea-modified, highly reactive phenolic resins

The inventive concept is to condense the phenol formaldehyde resins to a higher molecular weight than usual so far. Subsequent addition of urea thereto reduces viscosity to normal levels and increases solid content. The added urea does not take part in condensation reaction but partly reacts in the alkaline medium with formaldehyde to methylol urea (in a so called equilibrium reaction), which is formaldehyde donor for the phenol formaldehyde crosslinking reaction during the pressing of the particle board. The present invention relates to a process for producing modified phenolic resin bonding agents, characterized by preparing as known per se phenol-formaldehyde resins with a viscosity of more than 300 mPa.s (at 20.degree. C.) and with a solids content of from 65 weight percent and adding to the viscous phenolic resin solutions obtained 5 to 50 weight percent urea, based on the weight of the phenolic resin solution, the phenol formaldehyde resins being prepared with as much alkali as is required to secure that the modified resin solution resulting therefrom contains 2 to 12 weight percent total alkali calculated as NaOH. The solids content of the modified resin solutions ranges of from 20 to 65 weight percent, preferably of from 40 to 65 weight percent. The modified resin solutions prepared according to invention are bonding agents for producing particle boards, preferably triple- or multilayer particle boards. The modified resin solutions of the invention containing 2 to 6 weight percent alkali can be used as outer layer bonding agents. The modified resin solutions of the invention containing 2 to 6 weight percent alkali can be used in combination with isocyanate bonding agents as outer layer and particularly as center layer bonding agents, the bonding agents being applied to the particle either separately or jointly, the latter being preferred. The modified resin solutions of the invention containing more than 6 to 12 weight percent alkali can be used as outer layer and particularly as center layer bonding agents.

Process for producing modified phenolic resin bonding agents and use

A process for the manufacture of triple- and multi-layer particle board employing phenol formaldehyde resin compositions for gluing particles in the outer layers of the board characterized by the use of a phenol formaldehyde resin composition having a viscosity of about 30-90 seconds (4-mm DIN cup), a solids content of between about 30 and 39 percent by weight and an alkali content of less than 8 percent by weight is provided.

Process for the manufacture of multi-layer particle board using a phenol

In contrast to the known alkyd resins (fatty acid-modified polyesters) produced by way of esterification reaction, the alkyd resins according to this invention are produced by way of successive addition reactions. As a result, the structure and the chain length of the molecules can be predetermined, and the products obtained consist of uniform polyester molecules. Such products have viscosities lower than that of the known alkyd resins, thereby permitting the production of baking varnish systems comprising a low solvent content.

Process for preparing low viscosity fatty acid-modified polyesters

The present invention relates to a process for the manufacture of chip boards especially multi-layer chip boards, using condensation resins as binders, and the products thereof the improvement including wetting powdered adhesive particles before applying the adhesive particles to wood chips.

Growing community of inventors

Alpen, Germany

Adolf Buschfeld