Momentive Performance Materials Gmbh

Cornell University

Aaron M Tondreau

Paul J Chirik

Johannes G P Delis

Kenrick M Lewis

Susan Adams Nye

Keith James Weller

Richard W Cruse

Sarah Kathleen Russell

Johannes GP Delis

Disclosed herein is the selective synthesis of mono-hydrosilylated derivatives of polyunsaturated compounds, such as trivinylcyclohexane using non-precious metal based pyridinediimine and terpyridine complex as selective hydrosilylation catalysts.

Selective non-precious metal-catalyzed mono-hydrosilylation polyunsaturated compounds

Disclosed herein is a process for the hydrosilylation of a composition containing a silyl hydride and a compound containing at least one unsaturated group, the process comprising contacting a non-previous metal based complex as a catalyst precursor with an activator being a reducing agent shortly before, simultaneously or after contacting the complex with the composition, to cause the silyl hydride to react with the compound containing at least one unsaturated group to produce a hydrosilylation product.

In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts

Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.

Non-precious metal-containing 2,8-bis(imino)quinoline complexes and their use as hydrosilylation catalysts

Disclosed herein are metal-terpyridine complexes and their use in hydrosilylation reactions.

Hydrosilylation catalysts

Disclosed herein are manganese, iron, cobalt, or nickel complexes containing terdentate pyridine diimine ligands and their use as efficient and selective hydrosilylation catalysts.

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Zurich, Switzerland

Aaron M Tondreau